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• W2119939467 abstract "The Raman spectra of pure, anhydrous H2O2 and its deuteriated analogues, D2O2 and HDO2, were examined in the liquid state up to 40 °C and supercooled down to −75 °C. The OH (OD) stretching bands show a broad, single-peaked contour, and a strongly temperature-dependent asymmetry- Decomposition by analog computer reveals two overlapping bands, about 100 cm−1 apart, with different temperature behavior. In contrast with water, there is no indication in the hydrogen peroxide spectra of ‘free,’ i.e. non-hydrogen-bonded, OH groups, in keeping with the flexible geometry of the molecule and its electronic configuration. Based on these spectra, and by analogy with water, a two-state model is proposed featuring a continuum of hydrogen-bonded H2O2 molecules, with elose-packed OH groups in two kinds of environments. The hydrogen bonds are slightly weaker (12–15%) than those in water. Hydrogen peroxide is the best analog for studying the structure of water." @default.
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• W2119939467 date "1984-06-01" @default.
• W2119939467 modified "2023-09-26" @default.
• W2119939467 title "Hydrogen bonding in hydrogen peroxide and water. A Raman study of the liquid state" @default.
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• W2119939467 doi "https://doi.org/10.1002/jrs.1250150313" @default.
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