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- W2119954695 abstract "Calculations of polymerization kinetics and molecular weight development in the dithiolactone-mediated polymerization of styrene at 60 °C, using 2,2′-azobisisobutyronitrile (AIBN) as initiator and γ-phenyl-γ-butirodithiolactone (DTL1) as controller, are presented. The calculations were based on a polymerization mechanism based on the persistent radical effect, considering reverse addition only, implemented in the PREDICI® commercial software. Kinetic rate constants for the reverse addition step were estimated. The equilibrium constant (K = kadd/k-add) fell into the range of 105–106 L · mol−1. Fairly good agreement between model calculations and experimental data was obtained." @default.
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- W2119954695 date "2009-05-20" @default.
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- W2119954695 title "Kinetics and Molecular Weight Development of Dithiolactone-Mediated Radical Polymerization of Styrene" @default.
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- W2119954695 doi "https://doi.org/10.1002/mren.200900002" @default.
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