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• W2119966630 endingPage "8523" @default.
• W2119966630 startingPage "8516" @default.
• W2119966630 abstract "Phosphole-containing π-systems have emerged as building blocks with enormous potential as electronic materials because of the tunability of the phosphorus center. Among these, asymmetric P-bridged trans-stilbenes are still rare, and here an elegant and efficient synthesis toward such fluorescent molecular frameworks is described. Fine-tuning of the photophysical properties is attempted by enforcing the planarization of the phosphorus tripod and thus increasing the interaction between the phosphorus lone pair and the π-system. The electronic structure of the π-conjugated frameworks is analyzed with NMR, UV–vis and fluorescence spectroscopy, and time-dependent density functional theory (TD-DFT) calculations." @default.
• W2119966630 created "2016-06-24" @default.
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• W2119966630 date "2011-07-27" @default.
• W2119966630 modified "2023-09-27" @default.
• W2119966630 title "Ladder-Type <i>P</i>,<i>S</i>-Bridged <i>trans</i>-Stilbenes" @default.
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• W2119966630 doi "https://doi.org/10.1021/ic201116p" @default.
• W2119966630 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21793527" @default.
• W2119966630 hasPublicationYear "2011" @default.
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