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- W2120034054 abstract "Abstract Homochiral 2,2′-bis[4-(alkyl)oxazol-2-yl]-1,1′-binaphthyls, which possess both binaphthyl axial chirality and carbon centred chirality, were prepared from 1,1′-binaphthyl-2,2′-dicarboxylic acid and 2-alkyl-2-aminoethanols in high yields. Asymmetric cyclopropanation of styrene with diazoacetates in the presence of 2 mol % of copper(I) triflate and ( S )-2,2′-bis[( S )-4-( t -butyl)oxazol-2-yl]-1,1′-binaphthyl gave optically active 2-(phenyl)cyclopropane-carboxylates of up to 97% ee." @default.
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- W2120034054 date "1996-06-01" @default.
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- W2120034054 title "Homochiral 2,2′-bis(oxazolyl)-1,1′-binaphthyls as ligands for copper(I)-catalyzed asymmetric cyclopropanation" @default.
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- W2120034054 doi "https://doi.org/10.1016/0957-4166(96)00193-0" @default.
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