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- W2120070470 abstract "Abstract We have designed a new library of readily available, highly modular phosphite‐phosphoramidite ligands for asymmetric allylic substitution reactions. They are easily prepared in one step from commercially available chiral 1,2‐amino alcohols. The introduction of a phosphoramidite moiety into the ligand design is highly advantageous for the product outcome. This ligand library affords high reaction rates (TOFs of up to 800 mol (mol h) −1 ) and enantioselectivities ( ee s of up to 99 %) and, at the same time, contains a broad range of disubstituted hindered and unhindered substrate types. NMR study of the Pd‐π‐allyl intermediates provide a deeper understanding of the effect of the ligand parameters on the origin of enantioselectivity." @default.
- W2120070470 created "2016-06-24" @default.
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- W2120070470 date "2008-01-10" @default.
- W2120070470 modified "2023-10-18" @default.
- W2120070470 title "Screening of a Phosphite–Phosphoramidite Ligand Library for Palladium-Catalysed Asymmetric Allylic Substitution Reactions: The Origin of Enantioselectivity" @default.
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- W2120070470 doi "https://doi.org/10.1002/chem.200700852" @default.
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