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- W2120195890 abstract "Herein, high-generation dendrimers G4-NS and G5-NS, which contained 30 and 62 azo-benzene chromophore moieties, respectively, were conveniently prepared in high purity and satisfied yields by a combination of divergent and convergent approaches, coupled with the utilization of the powerful Sharpless click reaction. These dendrimers possessed a regular structure of alternating layers of nitro-based and sulfonyl-based azo chromophores in which the sulfonyl-based azo-chromophore moieties were utilized as co-isolation groups for the nitro-based moieties to achieve larger macroscopic second-order nonlinear optical (NLO) effects. These high-generation dendrimers (G4-NS and G5-NS) displayed very large NLO efficiencies (up to 253.0 pm V−1), which is, to the best of our knowledge, the record highest efficiency for simple azo-chromophore moieties." @default.
- W2120195890 created "2016-06-24" @default.
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- W2120195890 date "2012-07-24" @default.
- W2120195890 modified "2023-10-10" @default.
- W2120195890 title "High-Generation Second-Order Nonlinear Optical (NLO) Dendrimers that Contain Isolation Chromophores: Convenient Synthesis by Using Click Chemistry and their Increased NLO Effects" @default.
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- W2120195890 doi "https://doi.org/10.1002/chem.201200441" @default.
- W2120195890 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22829501" @default.
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