Matches in SemOpenAlex for { <https://semopenalex.org/work/W2120291263> ?p ?o ?g. }
- W2120291263 endingPage "5858" @default.
- W2120291263 startingPage "5858" @default.
- W2120291263 abstract "Novel mono- and ball-type Co(ii), Zn(ii) and Cu(ii) metallophthalocyanines (MPcs) were synthesized from 1,1'-p-anisylidenbis(2-naphthoxyphthalonitrile). The MPcs have been characterized by elemental analysis, UV/Vis, IR and (1)H-NMR spectroscopy and MALDI-TOF mass spectrometry. The performances of organic field effect transistors (OFETs) of the dinuclear ball-type MPcs have been compared to those of mononuclear counterparts. The ball-type MPc based OFETs showed a p-channel and typical ambipolar transport properties. On the other hand, it was not possible to measure the full transfer characteristics of the mononuclear MPc based devices. The best results were obtained in the case of dinuclear Cu2Pc2. In this case, the mobility value is μ = 4.4 × 10(-2) cm(2) V(-1) s(-1) and the threshold voltage is 27.6 volts. The reduction and oxidation characteristics of the mono-nuclear and ball-type MPcs have been compared by cyclic voltammetry, square wave voltammetry and controlled potential coulometry on platinum in nonaqueous media. The comparison suggested that the ball-type complexes form ring-based and/or metal-based mixed-valence species as a result of the remarkable interaction between the two Pc rings and/or metal centers. The stability of these species was confirmed by the mixed-valence splitting values for the complexes. The electrocatalytic performances of the mononuclear and dinuclear complexes for the oxygen reduction reaction were also studied. The compounds involving Co(ii) at the phthalocyanine core, especially the ball-type one, showed much higher catalytic performances towards oxygen reduction than those of the other ones." @default.
- W2120291263 created "2016-06-24" @default.
- W2120291263 creator A5002474452 @default.
- W2120291263 creator A5032135932 @default.
- W2120291263 creator A5034893854 @default.
- W2120291263 creator A5073543970 @default.
- W2120291263 creator A5074073996 @default.
- W2120291263 creator A5077287892 @default.
- W2120291263 date "2014-01-01" @default.
- W2120291263 modified "2023-10-18" @default.
- W2120291263 title "Synthesis, characterization, oxygen electrocatalysis and OFET properties of novel mono- and ball-type metallophthalocyanines" @default.
- W2120291263 cites W1979368277 @default.
- W2120291263 cites W1981815412 @default.
- W2120291263 cites W1981947363 @default.
- W2120291263 cites W1982784503 @default.
- W2120291263 cites W1982934023 @default.
- W2120291263 cites W1989848703 @default.
- W2120291263 cites W1999100919 @default.
- W2120291263 cites W1999847542 @default.
- W2120291263 cites W2003997576 @default.
- W2120291263 cites W2007954204 @default.
- W2120291263 cites W2012678800 @default.
- W2120291263 cites W2025279037 @default.
- W2120291263 cites W2027968999 @default.
- W2120291263 cites W2031903307 @default.
- W2120291263 cites W2038124595 @default.
- W2120291263 cites W2044016224 @default.
- W2120291263 cites W2046785344 @default.
- W2120291263 cites W2047591209 @default.
- W2120291263 cites W2050112682 @default.
- W2120291263 cites W2053912226 @default.
- W2120291263 cites W2054576473 @default.
- W2120291263 cites W2064939613 @default.
- W2120291263 cites W2085193403 @default.
- W2120291263 cites W2090004136 @default.
- W2120291263 cites W2100606752 @default.
- W2120291263 cites W2114216269 @default.
- W2120291263 cites W2145052816 @default.
- W2120291263 cites W2157315373 @default.
- W2120291263 cites W2169234518 @default.
- W2120291263 cites W2953304777 @default.
- W2120291263 doi "https://doi.org/10.1039/c3dt51955d" @default.
- W2120291263 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24577109" @default.
- W2120291263 hasPublicationYear "2014" @default.
- W2120291263 type Work @default.
- W2120291263 sameAs 2120291263 @default.
- W2120291263 citedByCount "20" @default.
- W2120291263 countsByYear W21202912632015 @default.
- W2120291263 countsByYear W21202912632016 @default.
- W2120291263 countsByYear W21202912632017 @default.
- W2120291263 countsByYear W21202912632018 @default.
- W2120291263 countsByYear W21202912632019 @default.
- W2120291263 countsByYear W21202912632021 @default.
- W2120291263 countsByYear W21202912632022 @default.
- W2120291263 countsByYear W21202912632023 @default.
- W2120291263 crossrefType "journal-article" @default.
- W2120291263 hasAuthorship W2120291263A5002474452 @default.
- W2120291263 hasAuthorship W2120291263A5032135932 @default.
- W2120291263 hasAuthorship W2120291263A5034893854 @default.
- W2120291263 hasAuthorship W2120291263A5073543970 @default.
- W2120291263 hasAuthorship W2120291263A5074073996 @default.
- W2120291263 hasAuthorship W2120291263A5077287892 @default.
- W2120291263 hasConcept C113196181 @default.
- W2120291263 hasConcept C121332964 @default.
- W2120291263 hasConcept C147789679 @default.
- W2120291263 hasConcept C17525397 @default.
- W2120291263 hasConcept C178790620 @default.
- W2120291263 hasConcept C185592680 @default.
- W2120291263 hasConcept C25621703 @default.
- W2120291263 hasConcept C2777869211 @default.
- W2120291263 hasConcept C2780761128 @default.
- W2120291263 hasConcept C33989665 @default.
- W2120291263 hasConcept C52859227 @default.
- W2120291263 hasConcept C540031477 @default.
- W2120291263 hasConcept C62520636 @default.
- W2120291263 hasConcept C82706917 @default.
- W2120291263 hasConceptScore W2120291263C113196181 @default.
- W2120291263 hasConceptScore W2120291263C121332964 @default.
- W2120291263 hasConceptScore W2120291263C147789679 @default.
- W2120291263 hasConceptScore W2120291263C17525397 @default.
- W2120291263 hasConceptScore W2120291263C178790620 @default.
- W2120291263 hasConceptScore W2120291263C185592680 @default.
- W2120291263 hasConceptScore W2120291263C25621703 @default.
- W2120291263 hasConceptScore W2120291263C2777869211 @default.
- W2120291263 hasConceptScore W2120291263C2780761128 @default.
- W2120291263 hasConceptScore W2120291263C33989665 @default.
- W2120291263 hasConceptScore W2120291263C52859227 @default.
- W2120291263 hasConceptScore W2120291263C540031477 @default.
- W2120291263 hasConceptScore W2120291263C62520636 @default.
- W2120291263 hasConceptScore W2120291263C82706917 @default.
- W2120291263 hasIssue "15" @default.
- W2120291263 hasLocation W21202912631 @default.
- W2120291263 hasLocation W21202912632 @default.
- W2120291263 hasOpenAccess W2120291263 @default.
- W2120291263 hasPrimaryLocation W21202912631 @default.
- W2120291263 hasRelatedWork W1972466433 @default.
- W2120291263 hasRelatedWork W1981405902 @default.
- W2120291263 hasRelatedWork W2027026165 @default.