Matches in SemOpenAlex for { <https://semopenalex.org/work/W2120302767> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W2120302767 endingPage "1944" @default.
- W2120302767 startingPage "1934" @default.
- W2120302767 abstract "Franck—Condon overlap integrals have been calculated which predict within experimental error the intensity distribution of the sixty measured lines in the visible fluorescence spectrum of molecular iodine, B 3Π0+u(v′ = 15, 16, or 26)→X 1Σ0+g(v″ = 0 to 69). Rydberg—Klein—Rees potentials were used for both electronic states, and exact vibrational eigenfunctions were obtained by direct numerical solution of the radial Schrödinger equation, including vibration—rotation interaction. The electronic transition moment was assumed to be independent of internuclear distance. Overlap integrals derived in the same way for Morse potentials fail to give even qualitative agreement with experiment for lines with v″≳10. Because of the rapid oscillation of the vibrational wavefunctions for high v′ and v″, a shift in the potential of only 0.002 Å is found to alter appreciably the calculated intensity distribution; thus the agreement obtained provides a very severe test of the RKR potentials and the Franck—Condon principle. The radiative lifetime of the B state has also been calculated from the absolute intensity of a single line and the integrated intensity of the band system, and the results compare favorably with direct lifetime measurements." @default.
- W2120302767 created "2016-06-24" @default.
- W2120302767 creator A5024513735 @default.
- W2120302767 date "1964-04-01" @default.
- W2120302767 modified "2023-09-26" @default.
- W2120302767 title "Calculation of Intensity Distribution in the Vibrational Structure of Electronic Transitions: The <i>B</i> 3Π+<i>u</i>—<i>X</i> 1Σ+<i>g</i> Resonance Series of Molecular Iodine" @default.
- W2120302767 cites W1595300442 @default.
- W2120302767 cites W1982845586 @default.
- W2120302767 cites W1987741147 @default.
- W2120302767 cites W1989335454 @default.
- W2120302767 cites W1994562286 @default.
- W2120302767 cites W2007882343 @default.
- W2120302767 cites W2009963039 @default.
- W2120302767 cites W2014868549 @default.
- W2120302767 cites W2015518990 @default.
- W2120302767 cites W2023887181 @default.
- W2120302767 cites W2028298752 @default.
- W2120302767 cites W2058708220 @default.
- W2120302767 cites W2066148764 @default.
- W2120302767 cites W2073033047 @default.
- W2120302767 cites W2082624809 @default.
- W2120302767 cites W2093894920 @default.
- W2120302767 cites W2137874850 @default.
- W2120302767 cites W2912279779 @default.
- W2120302767 cites W2914740196 @default.
- W2120302767 cites W98574139 @default.
- W2120302767 doi "https://doi.org/10.1063/1.1725425" @default.
- W2120302767 hasPublicationYear "1964" @default.
- W2120302767 type Work @default.
- W2120302767 sameAs 2120302767 @default.
- W2120302767 citedByCount "329" @default.
- W2120302767 countsByYear W21203027672012 @default.
- W2120302767 countsByYear W21203027672013 @default.
- W2120302767 countsByYear W21203027672014 @default.
- W2120302767 countsByYear W21203027672015 @default.
- W2120302767 countsByYear W21203027672016 @default.
- W2120302767 countsByYear W21203027672017 @default.
- W2120302767 countsByYear W21203027672018 @default.
- W2120302767 countsByYear W21203027672019 @default.
- W2120302767 countsByYear W21203027672020 @default.
- W2120302767 crossrefType "journal-article" @default.
- W2120302767 hasAuthorship W2120302767A5024513735 @default.
- W2120302767 hasConcept C113603373 @default.
- W2120302767 hasConcept C121332964 @default.
- W2120302767 hasConcept C128803854 @default.
- W2120302767 hasConcept C139210041 @default.
- W2120302767 hasConcept C158693339 @default.
- W2120302767 hasConcept C178790620 @default.
- W2120302767 hasConcept C181500209 @default.
- W2120302767 hasConcept C184779094 @default.
- W2120302767 hasConcept C185592680 @default.
- W2120302767 hasConcept C198352243 @default.
- W2120302767 hasConcept C198990423 @default.
- W2120302767 hasConcept C21074235 @default.
- W2120302767 hasConcept C2524010 @default.
- W2120302767 hasConcept C2775961149 @default.
- W2120302767 hasConcept C32909587 @default.
- W2120302767 hasConcept C33923547 @default.
- W2120302767 hasConcept C62520636 @default.
- W2120302767 hasConcept C93038891 @default.
- W2120302767 hasConceptScore W2120302767C113603373 @default.
- W2120302767 hasConceptScore W2120302767C121332964 @default.
- W2120302767 hasConceptScore W2120302767C128803854 @default.
- W2120302767 hasConceptScore W2120302767C139210041 @default.
- W2120302767 hasConceptScore W2120302767C158693339 @default.
- W2120302767 hasConceptScore W2120302767C178790620 @default.
- W2120302767 hasConceptScore W2120302767C181500209 @default.
- W2120302767 hasConceptScore W2120302767C184779094 @default.
- W2120302767 hasConceptScore W2120302767C185592680 @default.
- W2120302767 hasConceptScore W2120302767C198352243 @default.
- W2120302767 hasConceptScore W2120302767C198990423 @default.
- W2120302767 hasConceptScore W2120302767C21074235 @default.
- W2120302767 hasConceptScore W2120302767C2524010 @default.
- W2120302767 hasConceptScore W2120302767C2775961149 @default.
- W2120302767 hasConceptScore W2120302767C32909587 @default.
- W2120302767 hasConceptScore W2120302767C33923547 @default.
- W2120302767 hasConceptScore W2120302767C62520636 @default.
- W2120302767 hasConceptScore W2120302767C93038891 @default.
- W2120302767 hasIssue "7" @default.
- W2120302767 hasLocation W21203027671 @default.
- W2120302767 hasOpenAccess W2120302767 @default.
- W2120302767 hasPrimaryLocation W21203027671 @default.
- W2120302767 hasRelatedWork W1584610153 @default.
- W2120302767 hasRelatedWork W1973227600 @default.
- W2120302767 hasRelatedWork W2003943411 @default.
- W2120302767 hasRelatedWork W2007933047 @default.
- W2120302767 hasRelatedWork W2021903949 @default.
- W2120302767 hasRelatedWork W2041393669 @default.
- W2120302767 hasRelatedWork W2051681773 @default.
- W2120302767 hasRelatedWork W2998341793 @default.
- W2120302767 hasRelatedWork W3104194968 @default.
- W2120302767 hasRelatedWork W4200253396 @default.
- W2120302767 hasVolume "40" @default.
- W2120302767 isParatext "false" @default.
- W2120302767 isRetracted "false" @default.
- W2120302767 magId "2120302767" @default.
- W2120302767 workType "article" @default.