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- W2120549596 abstract "Abstract Desymmetrisation of silylcyclopenta‐2,4‐diene was carried out by an asymmetric copper( I )‐mediated cyclopropanation. An in‐depth investigation with various ligands led to the discovery that the PyBox ligands 10a − c were the most efficient ligands for this transformation and led to the cyclopropane 7a with an ee of up to 72%. Further studies aimed at providing insights into the origin of this enantiocontrol are also provided. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)" @default.
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- W2120549596 date "2003-02-26" @default.
- W2120549596 modified "2023-09-24" @default.
- W2120549596 title "Desymmetrisation of Cyclopentadienylsilane by Asymmetric Cyclopropanation" @default.
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- W2120549596 doi "https://doi.org/10.1002/ejoc.200390157" @default.
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