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- W2120621963 abstract "Solid-supported catalysts derived from homogeneous nickel(II) and palladium(II) non-symmetrical salen-type coordination complexes have been prepared and shown to be effective in the heterogeneous catalysis of carbon-carbon cross-coupling reactions. The nickel catalyst has been used in room-temperature Tamao-Kumada-Corriu reactions and the palladium catalyst in the Heck reaction at elevated temperatures. The complexes were prepared by improved methods and characterised by spectroscopic techniques. Comparisons between the solid-supported catalysts and their homogeneous analogues are reported. The single-crystal structure determination of the nickel and palladium complexes [M(salenac-OH)][M = Ni, Pd; salenac-OH = 9-(2',4'-dihydroxyphenyl)-5,8-diaza-4-methylnona-2,4,8-trienato](2-)] is reported." @default.
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- W2120621963 date "2004-01-01" @default.
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- W2120621963 title "Solid-supported cross-coupling catalysts derived from homogeneous nickel and palladium coordination complexesElectronic supplementary information (ESI) available: Synthesis of the complexes and crystallographic data for 1 and 2. See http://www.rsc.org/suppdata/dt/b3/b316553c/" @default.
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- W2120621963 doi "https://doi.org/10.1039/b316553c" @default.
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