Matches in SemOpenAlex for { <https://semopenalex.org/work/W2120671683> ?p ?o ?g. }
Showing items 1 to 72 of
72
with 100 items per page.
- W2120671683 endingPage "1553" @default.
- W2120671683 startingPage "1548" @default.
- W2120671683 abstract "The crystal structure of oxodichloropentane-2,4-dionatotriphenylphosphinerhenium(V) has been studied by single crystal X-ray methods. The crystals are triclinic with lattice parameters a = 11.023(8) Å, b = 13.523(8) Å, c = 9.360(7) Å, α = 90.2(1)°, β = 114.1(1)°, γ = 67.7(2)°. The space group is [Formula: see text] and there are two formula weights per unit cell. A total of 2891 reflections, of which 2447 were observed, were examined, and the structure was refined by full matrix least squares to an R 2 value of 0.0782. The ligands are arranged around the rhenium atom such that the nearest six atoms are at the corners of a very distorted octahedron. Most of this distortion appears to be caused by nonbonding repulsive interactions. The short oxo–phosphine distance, 2.85(1) Å, suggests the possibility of a weak bonding interaction. Observed bond distances (Re—Cl, 2.35 Å av; Re—O(oxo), 1.69(1) Å; Re—O(diketone), 1.99(1), 2.10(1) Å; Re—P, 2.431(4) Å) are close to those observed previously in similar compounds." @default.
- W2120671683 created "2016-06-24" @default.
- W2120671683 creator A5065115406 @default.
- W2120671683 creator A5086162980 @default.
- W2120671683 date "1975-06-01" @default.
- W2120671683 modified "2023-10-09" @default.
- W2120671683 title "Studies of β-Diketone Complexes of Rhenium. VII. The Crystal and Molecular Structure of Oxodichloropentane-2,4-dionatotriphenylphosphinerhenium(V)" @default.
- W2120671683 doi "https://doi.org/10.1139/v75-218" @default.
- W2120671683 hasPublicationYear "1975" @default.
- W2120671683 type Work @default.
- W2120671683 sameAs 2120671683 @default.
- W2120671683 citedByCount "18" @default.
- W2120671683 countsByYear W21206716832016 @default.
- W2120671683 countsByYear W21206716832019 @default.
- W2120671683 crossrefType "journal-article" @default.
- W2120671683 hasAuthorship W2120671683A5065115406 @default.
- W2120671683 hasAuthorship W2120671683A5086162980 @default.
- W2120671683 hasConcept C115624301 @default.
- W2120671683 hasConcept C155860418 @default.
- W2120671683 hasConcept C161790260 @default.
- W2120671683 hasConcept C178790620 @default.
- W2120671683 hasConcept C179104552 @default.
- W2120671683 hasConcept C185592680 @default.
- W2120671683 hasConcept C198819137 @default.
- W2120671683 hasConcept C199360897 @default.
- W2120671683 hasConcept C2777716191 @default.
- W2120671683 hasConcept C2781285689 @default.
- W2120671683 hasConcept C32909587 @default.
- W2120671683 hasConcept C41008148 @default.
- W2120671683 hasConcept C42228675 @default.
- W2120671683 hasConcept C505216180 @default.
- W2120671683 hasConcept C55493867 @default.
- W2120671683 hasConcept C71240020 @default.
- W2120671683 hasConcept C8010536 @default.
- W2120671683 hasConceptScore W2120671683C115624301 @default.
- W2120671683 hasConceptScore W2120671683C155860418 @default.
- W2120671683 hasConceptScore W2120671683C161790260 @default.
- W2120671683 hasConceptScore W2120671683C178790620 @default.
- W2120671683 hasConceptScore W2120671683C179104552 @default.
- W2120671683 hasConceptScore W2120671683C185592680 @default.
- W2120671683 hasConceptScore W2120671683C198819137 @default.
- W2120671683 hasConceptScore W2120671683C199360897 @default.
- W2120671683 hasConceptScore W2120671683C2777716191 @default.
- W2120671683 hasConceptScore W2120671683C2781285689 @default.
- W2120671683 hasConceptScore W2120671683C32909587 @default.
- W2120671683 hasConceptScore W2120671683C41008148 @default.
- W2120671683 hasConceptScore W2120671683C42228675 @default.
- W2120671683 hasConceptScore W2120671683C505216180 @default.
- W2120671683 hasConceptScore W2120671683C55493867 @default.
- W2120671683 hasConceptScore W2120671683C71240020 @default.
- W2120671683 hasConceptScore W2120671683C8010536 @default.
- W2120671683 hasIssue "11" @default.
- W2120671683 hasLocation W21206716831 @default.
- W2120671683 hasOpenAccess W2120671683 @default.
- W2120671683 hasPrimaryLocation W21206716831 @default.
- W2120671683 hasRelatedWork W1993881130 @default.
- W2120671683 hasRelatedWork W2006178578 @default.
- W2120671683 hasRelatedWork W2022450637 @default.
- W2120671683 hasRelatedWork W2052117432 @default.
- W2120671683 hasRelatedWork W2079168035 @default.
- W2120671683 hasRelatedWork W2086452220 @default.
- W2120671683 hasRelatedWork W2093647807 @default.
- W2120671683 hasRelatedWork W2308153341 @default.
- W2120671683 hasRelatedWork W2317778764 @default.
- W2120671683 hasRelatedWork W4231907785 @default.
- W2120671683 hasVolume "53" @default.
- W2120671683 isParatext "false" @default.
- W2120671683 isRetracted "false" @default.
- W2120671683 magId "2120671683" @default.
- W2120671683 workType "article" @default.