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- W2120691736 abstract "Noncovalent interactions play an essential role in biological and chemical processes. In the main chain of common protein secondary structures, the lone pair (n) of a carbonyl oxygen is delocalized into the antibonding orbital (π*) of the subsequent carbonyl group. Herein, experimental and computational data reveal that this n→π* interaction can be attenuated by the inductive electron withdrawal of one or two α-fluoro groups in the donor. The steric effect of three α-fluoro groups, however, overcomes the inductive withdrawal. These data evoke a means to modulate the n→π* interaction in peptides, proteins, and other systems." @default.
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- W2120691736 date "2010-07-08" @default.
- W2120691736 modified "2023-09-27" @default.
- W2120691736 title "Modulation of an n→π* interaction with α-fluoro groups" @default.
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- W2120691736 doi "https://doi.org/10.3998/ark.5550190.0011.817" @default.
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