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- W2120711882 abstract "LiFePO4 was synthesized by a high temperature method and high purity was confirmed by both powder X-ray diffraction and thermal analysis. It can deliver 136 Ah/kg, 80% of theoretical capacity at 1 mA/cm2 at high cathode load levels at room temperature; 100% capacity can be obtained by raising the temperature to 60 °C or reducing the discharge rate to 0.1 mA/cm2. The method of carbon addition/coating was not found to be critical, carbon black being as efficient as in situ formed carbon coatings. These materials suffer from a low volumetric energy density, which will seriously impact their possible application. Stabilized layered structures of manganese substituted nickel oxides, such as LiMn0.4Co0.2Ni0.4O2, show a behavior typical of a single phase intercalation reaction, and a reversible capacity of around 180 Ah/kg with an upper voltage cut-off of 4.3 V. Stabilized δ-structures of vanadium pentoxide show capacities approaching 300 Ah/kg, but with a median discharge potential of 2.6 V." @default.
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- W2120711882 date "2003-06-01" @default.
- W2120711882 modified "2023-10-14" @default.
- W2120711882 title "Performance of LiFePO4 as lithium battery cathode and comparison with manganese and vanadium oxides" @default.
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- W2120711882 doi "https://doi.org/10.1016/s0378-7753(03)00240-4" @default.
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