FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2120741366> ?p ?o ?g. }

• W2120741366 endingPage "15217" @default.
• W2120741366 startingPage "15211" @default.
• W2120741366 abstract "The different factors that control the alkene Prins cyclization catalyzed by iron(III) salts have been explored by means of a joint experimental-computational study. The iron(III) salt/trimethylsilyl halide system has proved to be an excellent promoter in the synthesis of crossed all-cis disubstituted tetrahydropyrans, minimizing the formation of products derived from side-chain exchange. In this iron(III)-catalyzed Prins cyclization reaction between homoallylic alcohols and non-activated alkenes, two mechanistic pathways can be envisaged, namely the classical oxocarbenium route and the alternative [2+2] cycloaddition-based pathway. It is found that the [2+2] pathway is disfavored for those alcohols having non-activated and non-substituted alkenes. In these cases, the classical pathway, via the key oxocarbenium ion, is preferred. In addition, the final product distribution strongly depends upon the nature of the substituent adjacent to the hydroxy group in the homoallylic alcohol, which can favor or hamper a side 2-oxonia-Cope rearrangement." @default.
• W2120741366 created "2016-06-24" @default.
• W2120741366 creator A5003674175 @default.
• W2120741366 creator A5005027591 @default.
• W2120741366 creator A5009883474 @default.
• W2120741366 creator A5053409116 @default.
• W2120741366 creator A5053738929 @default.
• W2120741366 creator A5077655105 @default.
• W2120741366 date "2015-09-10" @default.
• W2120741366 modified "2023-10-16" @default.
• W2120741366 title "Prins Cyclization Catalyzed by a Fe^III/Trimethylsilyl Halide System: The Oxocarbenium Ion Pathway versus the [2+2] Cycloaddition" @default.
• W2120741366 cites W1965351638 @default.
• W2120741366 cites W1966096776 @default.
• W2120741366 cites W1987006226 @default.
• W2120741366 cites W1989890247 @default.
• W2120741366 cites W1994013365 @default.
• W2120741366 cites W2015699145 @default.
• W2120741366 cites W2019679894 @default.
• W2120741366 cites W2020618574 @default.
• W2120741366 cites W2038802224 @default.
• W2120741366 cites W2047846520 @default.
• W2120741366 cites W2049131878 @default.
• W2120741366 cites W2051056308 @default.
• W2120741366 cites W2053026543 @default.
• W2120741366 cites W2055264554 @default.
• W2120741366 cites W2063633829 @default.
• W2120741366 cites W2067714867 @default.
• W2120741366 cites W2070810674 @default.
• W2120741366 cites W2085071575 @default.
• W2120741366 cites W2086278769 @default.
• W2120741366 cites W2089576441 @default.
• W2120741366 cites W2096699107 @default.
• W2120741366 cites W2103283253 @default.
• W2120741366 cites W2105128797 @default.
• W2120741366 cites W2107796725 @default.
• W2120741366 cites W2114760492 @default.
• W2120741366 cites W2123542291 @default.
• W2120741366 cites W2126868371 @default.
• W2120741366 cites W2131568271 @default.
• W2120741366 cites W2134579742 @default.
• W2120741366 cites W2138623672 @default.
• W2120741366 cites W2138787814 @default.
• W2120741366 cites W2148221544 @default.
• W2120741366 cites W2149812179 @default.
• W2120741366 cites W2154686013 @default.
• W2120741366 cites W2163276596 @default.
• W2120741366 cites W2168081014 @default.
• W2120741366 cites W2175559768 @default.
• W2120741366 cites W2175814728 @default.
• W2120741366 cites W2322766702 @default.
• W2120741366 cites W2323904363 @default.
• W2120741366 cites W2734547407 @default.
• W2120741366 cites W2949899255 @default.
• W2120741366 cites W2950677182 @default.
• W2120741366 cites W2950885813 @default.
• W2120741366 cites W2950952676 @default.
• W2120741366 cites W2951214847 @default.
• W2120741366 cites W2951338743 @default.
• W2120741366 cites W2952392876 @default.
• W2120741366 cites W2952483711 @default.
• W2120741366 cites W2952608823 @default.
• W2120741366 cites W2952734119 @default.
• W2120741366 cites W2952968848 @default.
• W2120741366 cites W3004602673 @default.
• W2120741366 cites W3005434895 @default.
• W2120741366 cites W4211180255 @default.
• W2120741366 cites W4231876709 @default.
• W2120741366 cites W4242948453 @default.
• W2120741366 cites W4255634158 @default.
• W2120741366 doi "https://doi.org/10.1002/chem.201502488" @default.
• W2120741366 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26471437" @default.
• W2120741366 hasPublicationYear "2015" @default.
• W2120741366 type Work @default.
• W2120741366 sameAs 2120741366 @default.
• W2120741366 citedByCount "22" @default.
• W2120741366 countsByYear W21207413662016 @default.
• W2120741366 countsByYear W21207413662017 @default.
• W2120741366 countsByYear W21207413662018 @default.
• W2120741366 countsByYear W21207413662019 @default.
• W2120741366 countsByYear W21207413662020 @default.
• W2120741366 countsByYear W21207413662021 @default.
• W2120741366 countsByYear W21207413662022 @default.
• W2120741366 countsByYear W21207413662023 @default.
• W2120741366 crossrefType "journal-article" @default.
• W2120741366 hasAuthorship W2120741366A5003674175 @default.
• W2120741366 hasAuthorship W2120741366A5005027591 @default.
• W2120741366 hasAuthorship W2120741366A5009883474 @default.
• W2120741366 hasAuthorship W2120741366A5053409116 @default.
• W2120741366 hasAuthorship W2120741366A5053738929 @default.
• W2120741366 hasAuthorship W2120741366A5077655105 @default.
• W2120741366 hasBestOaLocation W21207413662 @default.
• W2120741366 hasConcept C155647269 @default.
• W2120741366 hasConcept C161790260 @default.
• W2120741366 hasConcept C17112743 @default.
• W2120741366 hasConcept C178790620 @default.
• W2120741366 hasConcept C178907741 @default.
• W2120741366 hasConcept C185592680 @default.
• W2120741366 hasConcept C196647687 @default.

• next