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- W2120765130 abstract "Improved methods have been developed for generating aliphatic ketyl radical anions in solution for study by EPR spectroscopy. These methods involve either photolysis of a solution of potassium in the corresponding alcohol (which probably proceeds by initial electron transfer to the solvent), or abstraction of a hydrogen atom from the corresponding alcohol by photolytically generated tert-butoxyl radicals under strongly basic conditions. The EPR spectra of a number of new aldehyde and ketone radical ions are described, and compared with the spectra of their conjugate acids. The value of a(13C-α) in the acetone radical anion is found to be 52.2 G confirming that it is non-planar. The Arrhenius parameters for the inversion of the ring in the cyclohexanone radical anion are Ea= 6.6 kcal mol–1, and log (A/s–1)= 13.2." @default.
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- W2120765130 date "1992-01-01" @default.
- W2120765130 modified "2023-10-14" @default.
- W2120765130 title "Electron paramagnetic resonance spectra of aliphatic ketyl radical anions in fluid solution" @default.
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- W2120765130 doi "https://doi.org/10.1039/p29920000163" @default.
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