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- W2120881828 abstract "Experiments were made to investigate the effect of experimental conditions on the forms of Al adsorbed from solution by clays. It was found that when Ca(OH) 2 was added to suspensions of clay in approximately 10 −2 M solutions of AlCl 3 , the titration curves of the 2 N NaCl extracts of the clays showed one buffer zone between pH 4 and 5. If the Ca(OH) 2 was mixed with the AlCl 3 solution before adding the clay, the titration curves of the NaCl extracts showed, besides the normal buffer zone between pH 4 and 5, a second one near pH 6. Since the Al material that titrated near pH 6 was formed in the mixtures of Ca(OH) 2 and AlCl 3 , removed from the dilute salt solutions by clay and released again to 2 N NaCl, it was assumed to be positively charged, exchangeable, polymeric Al ions. These polymeric ions were depolymerized and measured as monomers by the aluminon method. Heating the clay-AlCl 3 suspensions, to which Ca(OH) 2 had been added, to 100 °C also produced these exchangeable, polymeric Al ions but in this case they were not depolymerized and measured by the aluminon method." @default.
- W2120881828 created "2016-06-24" @default.
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- W2120881828 date "1967-10-01" @default.
- W2120881828 modified "2023-09-26" @default.
- W2120881828 title "ALUMINUM REMOVED FROM SOLUTION BY MONTMORILLONITE" @default.
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- W2120881828 doi "https://doi.org/10.4141/cjss67-034" @default.
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