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- W2120922990 abstract "Reactions of the cationic arene complexes [(C6H6 –nMen)Mn(CO)3]+ with cyanide ion under mild conditions yield exo-cyanocyclohexadienyl complexes (C6H6 –nMenCN)Mn(CO)3 in which the cyano-group is attached to an unsubstituted carbon atom: the hexamethylbenzene complex reacts differently to form (C6Me6)Mn(CO)2CN. The preference for addition to an unsubstituted carbon atom is (at least in part) kinetic rather than thermodynamic in origin, since the compound formed by cyanide addition to the mesitylene complex rearranges in chloroform solution to give some of the isomer in which the cyano-group is attached to a methyl-substituted carbon atom." @default.
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- W2120922990 date "1973-01-01" @default.
- W2120922990 modified "2023-10-11" @default.
- W2120922990 title "Formation and reactions of cyanocyclohexadienyl complexes of manganese(I)" @default.
- W2120922990 doi "https://doi.org/10.1039/dt9730000622" @default.
- W2120922990 hasPublicationYear "1973" @default.
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