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- W2120952817 abstract "Silicon carbide (SiC) films were prepared from methyltrichlorosilane (MTS) and H2 at temperatures ranging from 900 to 1000◦C by low-pressure chemical vapor deposition (CVD). Multi-scale analysis was performed on the SiC film growth rate using a growth rate profile for a tubular reactor that was 300 mm long from the inlet to the outlet and a step coverage (SC) profile for micron-sized trenches. The precursor consumption ratio was estimated using a quadrupole mass spectrometer (QMS). These systematic analyses revealed that MTS was not the direct growth species for SiC deposition. We concluded that there were two major growth species controlling the SiC deposition rate. The partial pressures of these species were estimated by SC and growth rate analyses. An elementary reaction simulation was performed to predict the SiC film growth species. A comparison between the elementary reaction simulation results and the multi-scale analysis suggested several chemical species as candidates for the direct growth species. The candidates for the first species, with a low sticking probability of around 10 −3 ,w ere CH4 ,C 2H4 ,a nd C2H2, and candidates for the second species, with a high sticking probability of around 10 −1 ,w ere CH3 ,C 2H3 ,a nd C2H5." @default.
- W2120952817 created "2016-06-24" @default.
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- W2120952817 date "2013-01-01" @default.
- W2120952817 modified "2023-09-30" @default.
- W2120952817 title "Multi-Scale Analysis and Elementary Reaction Simulation of SiC-CVD Using CH3SiCl3/H2" @default.
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- W2120952817 doi "https://doi.org/10.1149/2.039311jss" @default.
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