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• W2121083711 abstract "Infrared (IR) laser spectroscopy is used to probe the rotational and vibrational dynamics of the (HCN)m−Mn (M = K, Ca, Sr) complexes, either solvated within or bound to the surface of helium nanodroplets. The IR spectra of the (HCN)m−K (m = 1−3), HCN−Sr, and HCN−Ca complexes have the signature of a surface species, similar to the previously reported spectra of HCN−M (M = Na, K, Rb, Cs) [Douberly, G. E.; Miller, R. E. J. Phys. Chem. A 2007, 111, 7292.]. A second band in the HCN−Ca spectrum is assigned to a solvated complex. The relative intesities of the two HCN−Ca bands are droplet size dependent, with the solvated species being favored in larger droplets. IR−IR double resonance spectroscopy is used to probe the interconversion of the two distinct HCN−Ca populations. While only a surface-bound HCN−Sr species is initially produced, CH stretch vibrational excitation results in a population transfer to a solvated state. Complexes containing multiple HCN molecules and one Sr atom are surface-bound, while the ν1 (HCN)2Ca spectrum has both the solvated and surface-bound signatures. All HCN−(Ca,Sr)n (n ≥ 2) complexes are solvated following cluster formation in the droplet. Density-functional calculations of helium nanodroplets interacting with the HCN−M show surface binding for M = Na with a binding energy of 95 cm−1. The calculations predict a fully solvated complex for M = Ca. For M = Sr, a 2.2 cm−1 barrier is predicted between nearly isoenergetic surface binding and solvated states." @default.
• W2121083711 created "2016-06-24" @default.
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• W2121083711 date "2010-02-12" @default.
• W2121083711 modified "2023-09-23" @default.
• W2121083711 title "(HCN)_<i>m</i>−M_<i>n</i> (M = K, Ca, Sr): Vibrational Excitation Induced Solvation and Desolvation of Dopants in and on Helium Nanodroplets" @default.
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• W2121083711 doi "https://doi.org/10.1021/jp908834m" @default.
• W2121083711 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20151690" @default.
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