Matches in SemOpenAlex for { <https://semopenalex.org/work/W2121306104> ?p ?o ?g. }
Showing items 1 to 67 of
67
with 100 items per page.
- W2121306104 endingPage "915" @default.
- W2121306104 startingPage "912" @default.
- W2121306104 abstract "Die Titelverbindung 4 wird, ausgehend vom 7-Chlorthienopyridin 1, über die 7-Dimethoxybenzylverbindung 2 synthetisiert, die durch Wittig-Alkylierung hergestellt wird. 2 wird mit Methyliodid zum Iminiumsalz 3 methyliert, das mit LiAlH4 zu 4 reduziert wird. Bei Behandlung mit 0,1 N-HCl entstehen aus 4 die Disproportionierungsprodukte 3 und 5, daneben wird in 6-proz. Ausbeute das Umlagerungsprodukt 6 erhalten, das als Pseudocyanid 7 isoliert wurde. Diydroisoquinoline Rearrangement, XXXV: 6,7-Dibydro-7-(3,4-dimethoxybenzyl)-6-methylthieno[2,3-c]pyridine The title compound 4 is synthesized from the 7-chlorothienopyridine 1 via the 7-(dimethoxybenzyl) compound 2 which is obtained by Wittig alkylation. Compound 2 is methylated by methyl iodide to give the iminium salt 3 which is reduced with LiAIH4 to yield 4. When 4 is treated with 0,l N-HCI the disproportionation products 3 and 5 are formed. Moreover, the rearrangement product 6 is obtained in 6% yield. Compound 6 was isolated as the pseudocyanide 7." @default.
- W2121306104 created "2016-06-24" @default.
- W2121306104 creator A5044346485 @default.
- W2121306104 creator A5088301650 @default.
- W2121306104 date "1983-01-01" @default.
- W2121306104 modified "2023-09-27" @default.
- W2121306104 title "Dihydroisochinolinumlagerung, 35. Mitt.1) 7-(3,4-Dimethoxybenzyl)-6-methyl-6,7-dihydrothieno [2,3-c]pyridin" @default.
- W2121306104 cites W1970819866 @default.
- W2121306104 cites W2016407668 @default.
- W2121306104 cites W2022468623 @default.
- W2121306104 cites W2036009650 @default.
- W2121306104 cites W2063044815 @default.
- W2121306104 cites W2095036612 @default.
- W2121306104 cites W2102593942 @default.
- W2121306104 doi "https://doi.org/10.1002/ardp.19833161104" @default.
- W2121306104 hasPublicationYear "1983" @default.
- W2121306104 type Work @default.
- W2121306104 sameAs 2121306104 @default.
- W2121306104 citedByCount "4" @default.
- W2121306104 crossrefType "journal-article" @default.
- W2121306104 hasAuthorship W2121306104A5044346485 @default.
- W2121306104 hasAuthorship W2121306104A5088301650 @default.
- W2121306104 hasConcept C134121241 @default.
- W2121306104 hasConcept C155647269 @default.
- W2121306104 hasConcept C161790260 @default.
- W2121306104 hasConcept C164361826 @default.
- W2121306104 hasConcept C178790620 @default.
- W2121306104 hasConcept C185592680 @default.
- W2121306104 hasConcept C191897082 @default.
- W2121306104 hasConcept C192562407 @default.
- W2121306104 hasConcept C24292678 @default.
- W2121306104 hasConcept C2779485729 @default.
- W2121306104 hasConcept C2780073701 @default.
- W2121306104 hasConcept C71240020 @default.
- W2121306104 hasConceptScore W2121306104C134121241 @default.
- W2121306104 hasConceptScore W2121306104C155647269 @default.
- W2121306104 hasConceptScore W2121306104C161790260 @default.
- W2121306104 hasConceptScore W2121306104C164361826 @default.
- W2121306104 hasConceptScore W2121306104C178790620 @default.
- W2121306104 hasConceptScore W2121306104C185592680 @default.
- W2121306104 hasConceptScore W2121306104C191897082 @default.
- W2121306104 hasConceptScore W2121306104C192562407 @default.
- W2121306104 hasConceptScore W2121306104C24292678 @default.
- W2121306104 hasConceptScore W2121306104C2779485729 @default.
- W2121306104 hasConceptScore W2121306104C2780073701 @default.
- W2121306104 hasConceptScore W2121306104C71240020 @default.
- W2121306104 hasIssue "11" @default.
- W2121306104 hasLocation W21213061041 @default.
- W2121306104 hasOpenAccess W2121306104 @default.
- W2121306104 hasPrimaryLocation W21213061041 @default.
- W2121306104 hasRelatedWork W2028099705 @default.
- W2121306104 hasRelatedWork W2039941721 @default.
- W2121306104 hasRelatedWork W2067428994 @default.
- W2121306104 hasRelatedWork W2097014657 @default.
- W2121306104 hasRelatedWork W2334405616 @default.
- W2121306104 hasRelatedWork W2402425649 @default.
- W2121306104 hasRelatedWork W2887432323 @default.
- W2121306104 hasRelatedWork W2952076161 @default.
- W2121306104 hasRelatedWork W3190990114 @default.
- W2121306104 hasRelatedWork W4213310706 @default.
- W2121306104 hasVolume "316" @default.
- W2121306104 isParatext "false" @default.
- W2121306104 isRetracted "false" @default.
- W2121306104 magId "2121306104" @default.
- W2121306104 workType "article" @default.