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- W2121364680 abstract "Die Carbanionen von 1,1-Disulfon-äthanen (1a, 1b) oder Halogen-disulfon-methanen (1e) reagieren mit α-Halogenäthern unter Bildung von 1-Alkoxy-2,2-disulfon-propanen (3a, 3b) bzw. 1-Halogen-1,1-disulfon-2-alkoxy-äthanen (3e). Aus Diäthylsulfon-methan und Chlormethyläther entsteht 1,3-Bismethoxy-2,2-bisäthylsulfon-propan (6b). 1-Alkoxy-2,2-disulfon-propane (3a, 3d) sind auch zugänglich durch Oxidation der mittles Kondensation von Alkoxy-aceton (4) und Mercaptanen erhaltenen Mercaptale 5. 1-Alkoxymethyl-1.1-bissulfonyl Alkanes Via the carbanions of 1.1-bissulfonyl ethanes (1a, 1b) and bissulfonyl halomethanes (1e) with α-haloethers, 1-alkoxy-2.2-bissulfonyl propanes (3a, 3b) and 1-halo-1.1-bissulfonyl-2-alkoxyethanes (3e) are prepared. From diethylsulfonyl methane and chloromethyl ether results 1.3-bismethoxy-2.2-bisethylsulfonyl propane (6b). 1-Alkoxy-2.2-bissulfonyl propanes (3a, 3d) are also formed by oxidation of the thioacetals 5 which have been obtained by condensation of mercaptans with alkoxyacetone (4)." @default.
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- W2121364680 date "1972-01-01" @default.
- W2121364680 modified "2023-09-27" @default.
- W2121364680 title "Über Alkoxymethyl-disulfon-alkane" @default.
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- W2121364680 doi "https://doi.org/10.1002/ardp.19723051211" @default.
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