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• W2121474570 abstract "The laser flash photolysis of indole at 265 nm in the presence of glycine, proline and hydroxy proline was studied. The relative yields of c aq, triplet state, and indole cation radical were determined in the absence and in the presence of the amino acids. The yields were determined as a function of laser intensity and the values at very low intensity were compared with the fluorescence quenching results. It was concluded that in these conditions the photoionization of indole occurs via the fluorescent state. From the curves of triplet yield vs laser intensity, the triplet quantum yield extrapolated at low laser intensity was obtained, φr = 0.55 φ 0.05, relative to the literature value of 0.15 for φeag. This gives φF+φeaq= 1.0 ± 0.1 at room temperature. When proline and hydroxy proline were used as singlet quenchers, the yield of In was greater than the yield of caq. This was considered as evidence that a fraction of the quenching processes leads to complete electron transfer from indole to the amino acids." @default.
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• W2121474570 creator A5043748902 @default.
• W2121474570 date "1984-12-01" @default.
• W2121474570 modified "2023-09-27" @default.
• W2121474570 title "LASER FLASH PHOTOLYSIS OF INDOLE IN THE PRESENCE OF AMINO ACIDS" @default.
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• W2121474570 doi "https://doi.org/10.1111/j.1751-1097.1984.tb04638.x" @default.
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