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• W2121487788 abstract "The UV, preresonance Raman, and IR spectra of the stable silene t-BuMe2Si(Me3Si)Si2-Ad (1) have been measured as well as its JSiC NMR coupling constant. The normal modes involving the ν(SiC) stretching coordinate were identified for the first time for a stable silene. The experimental data and computations of potential energy distribution and mode eigenvectors show that there is no single vibrational normal mode which can be assigned as ν(SiC). Raman intensity enhancement on approaching resonance strongly supports the conclusion that there are five lines in the region 1000−1370 cm-1 which include significant contribution from the ν(SiC) stretching coordinate. Both the SiC force constant and the JSiC NMR coupling constant (as well as the SiC bond length) indicate that the SiC bond order is smaller in 1 than that in simpler silenes of the type R2SiCH2 (R = H, Me)." @default.
• W2121487788 created "2016-06-24" @default.
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• W2121487788 date "2002-04-24" @default.
• W2121487788 modified "2023-09-24" @default.
• W2121487788 title "The Raman, Ultraviolet, and Infrared Spectra and the <i>J</i>_Si_C NMR Coupling Constant of the Stable Silene (<i>t</i>-BuMe₂Si)(Me₃Si)Si2-Ad. Manifestations of the SiC Double Bond" @default.
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• W2121487788 doi "https://doi.org/10.1021/jp014158x" @default.
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