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- W2121569313 abstract "Regioselectivity on the reactions of <TEX>${alpha},{beta}$</TEX>--enones with organoindium such as in situ generated allylindium and allenylindium was systematically studied in the presence of TMSCl as an additive. Treatment of 2-cyclohexen-1-one, carvone, 2-cyclohepten-1-one, and chalcone with allylindium reagent produced 1,4-addition products in good yields, while 2-cyclopenten-1-one, 2-methyl-2-cyclopenten-1-one, 4,4-dimethylcyclohexen-1-one, 3-nonen-2-one, 4-hexen-3-one, and 4-phenyl-3-buten-2-one afforded 1,2-addition products. Indium reagent derived from indium and propargyl bromide in Grignard type gave addition products in good yields, under which the successive addition of <TEX>${alpha},{beta}$</TEX>-enone and TMSCl were necessary. Although organoindium reagent derived from propargyl bromide produced propargylated compound in Grignard type except 2-cyclohepten-1-one, indium reagent obtained from 1-bromo-2-butyne having <TEX>${gamma}$</TEX>-methyl group gave allenylated product inBarbier type." @default.
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- W2121569313 date "2004-11-20" @default.
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- W2121569313 title "Regioselective Addition Reactions of the Organoindium Reagents onto α,β-Unsaturated Ketones" @default.
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- W2121569313 doi "https://doi.org/10.5012/bkcs.2004.25.11.1687" @default.
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