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- W2121574105 abstract "The kinetics of oxidation of antihypertensive drug, atenolol by diperiodatoargentate(III) (DPA) in a wide range of alkali has been studied spectrophotometrically. In a lower range of [OH−], the periodate had a retarding effect whereas at higher range of [OH−] the rate of reaction was accelerated. In the higher range of [OH−], the periodate had no effect whereas at lower range of [OH−], periodate and product, [Ag(I)] retarded the rate of the reaction. In the entire range of [OH−], the reaction was unit order in [DPA] and fractional order in [ATN]. Mechanisms consistent with the observed kinetic data for both lower and higher ranges of [OH−] were proposed and discussed. The active species of [Ag(III)] was found to be mono periodatoargentate(III) in lower range of [OH−] and dihydroxymonodiperiodatoargentate(III) in the higher range of [OH−]. The hydrolyzed species of atenolol was found to be the active form of atenolol. Mechanisms for both higher and lower range of [OH−] have been proposed. A composite rate ..." @default.
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- W2121574105 date "2008-06-01" @default.
- W2121574105 modified "2023-09-23" @default.
- W2121574105 title "Oxidation of atenolol by diperiodatoargentate(III) in aqueous alkaline medium – a multimechanistic reaction" @default.
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- W2121574105 doi "https://doi.org/10.1080/10241220802213902" @default.
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