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• W2121725722 abstract "The 105 K second&order displacive phase transition of SrTiO 3 has been studied with the help of Electron Paramagnetic Resonance. The photochromic non&cubic Fe 5+ centre is used as local probe. Critical phenomena, characterized by an exponent β = 1/3, are presented. Line broadening effects are interpreted as stemming from time&dependent fluctua tions near the phase transition point. The data are consistent with those reported earlier on the Fe 3+ &V O pair centre, indicating cooperative effects in the crystal. Also a model for the non&cubic Fe 5+ is proposed, i.e., the ion is substitutional for Ti 4+ with an empty adjacent expanded octahedron. Other Fe 5+ centres in SrTiO 3 and BaTiO 3 are reviewed and reinterpreted." @default.
• W2121725722 created "2016-06-24" @default.
• W2121725722 creator A5061004403 @default.
• W2121725722 date "2012-01-16" @default.
• W2121725722 modified "2023-09-27" @default.
• W2121725722 title "EPR studies of the 105 K phase transition of SrTiO3 with the non-cubic Fe5+ as local probe and a reinterpretation of other Fe5+ centres" @default.
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