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- W2121752621 abstract "The influence of dissolution of a segregating element (Sb) in a metal matrix in which oxide precipitates are present on the precipitate morphology and the interface structure is studied using HRTEM. The influence on Mn 3 O 4 precipitates in Ag is distinct: (i) the initial precipitates, sharply facetted by solely {111}, are changed into a globular shape with sometimes also short {220} and (002) facets, (ii) a partly reduction of Mn 3 O 4 into MnO occurs for a part of the precipitates. Further Sb appeared to prevent Oswald ripening of the precipitates. The influence on MnO and MgO precipitates in Cu is more subtle: only a small but significant increase of the facet lengths of the {200} (and {220}) relative to the {111} occurs. The influence of Sb can be explained by a large decrease of the energy of steps at Ag/Mn 3 O 4 interfaces and by a stronger tendency for segregation of Sb to {200} and {220} than to {111} facets of the Ag/Mn 3 O 4 , Cu/MnO and Cu/MgO interfaces." @default.
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- W2121752621 date "1998-11-01" @default.
- W2121752621 modified "2023-09-27" @default.
- W2121752621 title "Modification of Metal/Oxide Interfaces by Dissolution of Sb in Oxide Precipitates Containing Metal Matrices" @default.
- W2121752621 doi "https://doi.org/10.4028/www.scientific.net/msf.294-296.255" @default.
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