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- W2121782165 abstract "Abstract The heterocyclic diols derived from L-dimethyl tartrate are important chiral synthons in organic synthesis. In particular, L-threosolactone and L-threosolactam structures are versatile precursors for the synthesis of biologically active molecules. Structurally, these functionalized five-membered rings contain two hydroxyl groups with R and S stereochemistry on C-2 and C-3 respectively. The preparation of (2R,3S)-2-benzyloxy-3-hydroxybutyrolactone (3) and of its derivatives, drawing upon L-dimethyl tartrate as an inexpensive chiral starting material, is described. The presented synthetic procedures are easy and effective for preparing L-threoso analogs. This protocol is also a better alternative in a large scale setup. All structures 3–6 and 8 are characterized using 1H and 13C NMR spectroscopy." @default.
- W2121782165 created "2016-06-24" @default.
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- W2121782165 date "2013-06-03" @default.
- W2121782165 modified "2023-10-16" @default.
- W2121782165 title "Facile Synthesis of (2R,3S)-2-Benzyloxy-3-hydroxybutyrolactone" @default.
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- W2121782165 doi "https://doi.org/10.1080/00397911.2012.714041" @default.
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