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- W2121973578 abstract "(MeF) [593-53-3] CH3F (MW 34.04)InChI = 1S/CH3F/c1-2/h1H3InChIKey = NBVXSUQYWXRMNV-UHFFFAOYSA-N(SbF5) [7783-70-2] F5Sb (MW 216.75)InChI = 1S/5FH.Sb/h5*1H;/q;;;;;+5/p-5InChIKey = VBVBHWZYQGJZLR-UHFFFAOYSA-I(reactive methylating agent;1 Friedel–Crafts type electrophilic methylations; preparation of onium salts)Physical Data: MeF: bp −78.2 °C; SbF5: bp 149.5 °C.Form Supplied in: MeF: gas; SbF5: viscous liquid. Both are commercially available.Preparative Methods: prepared by mixing equimolar amounts of freshly distilled MeF and Antimony(V) Fluoride in SO2F2 solution at low temperature.2 The reagent can also be prepared in situ in the reaction flask.Handling, Storage, and Precautions: corrosive, moisture sensitive, and potentially carcinogenic. Thus, caution should be exercised accordingly. Use in a fume hood." @default.
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- W2121973578 date "2001-04-15" @default.
- W2121973578 modified "2023-09-27" @default.
- W2121973578 title "Methyl Fluoride-Antimony(V) Fluoride" @default.
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- W2121973578 doi "https://doi.org/10.1002/047084289x.rm187" @default.
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