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- W2122014399 abstract "Single crystal X-ray structures have been obtained for [Ag(L-cysteic acid)] [Formula: see text] (1) and [Ag(L-cysteic acid)(H 2 O)] [Formula: see text] (2) These compounds represent the first two structurally characterized complexes of cysteic acid. Network 1 is shown to adopt an infinite two-dimensional structure, describable as one-dimensional ribbons cross-linked into layers. The basic building block is a doubly carboxylate-bridged silver(I) dimer. Compound 1 crystallizes in the monoclinic space group P2 1 (a = 5.5066(3) Å, b = 7.5761(4) Å, c = 16.644(1) Å, β = 94.335(1)°). Compound 2, while differing chemically from 1 by only one water molecule, forms a three-dimensional structure built upon the same core dimer unit as that observed in 1. In 2, these units assemble in a different manner via the weak interactions and form a channel structure in which the guest water molecules are included. Compound 2 crystallizes in the monoclinic space group P2 1 (a = 8.120(2) Å, b = 9.805(2) Å, c = 9.204(2) Å, β = 98.45(3)°).Key words: silver, carboxylates, sulfonates, coordination polymer." @default.
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- W2122014399 date "2002-11-01" @default.
- W2122014399 modified "2023-09-27" @default.
- W2122014399 title "Condensed versus open channel structures in cysteic acid coordination frameworks containing d<sup>10</sup>-d<sup>10</sup> dimers" @default.
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- W2122014399 doi "https://doi.org/10.1139/v02-148" @default.
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