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- W2122116780 abstract "The dielectric constant of non-polar fluids does not agree with the Clausius-Mossotti formula. The deviation is calculated taking the induced dipole-dipole interactions into consideration. Since the induced dipole moments suggest that the molecules are most likely deformed, the theories developed by Kirkwood, Yvon and others 4) are generalized in this paper to treat non-spherical molecules. A new mathematical method is introduced, and the dielectric constant is calculated as a function of the molecular anisotropy. In particular, the so-called rotational fluctuation is found to be composed of two terms, one representing the optical and the other corresponding to the geometrical anisotropy." @default.
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- W2122116780 title "Theory of dielectric polarization in non-polar fluids" @default.
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- W2122116780 doi "https://doi.org/10.1016/0031-8914(61)90083-0" @default.
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