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• W2122137790 endingPage "15932" @default.
• W2122137790 startingPage "15920" @default.
• W2122137790 abstract "Macrocycles such as porphyrins and corroles have important functions in chemistry and biology, including light absorption for photosynthesis. Generation of near-IR (NIR)-absorbing dyes based on metal complexes of these macrocycles for mimicking natural photosynthesis still remains a challenging task. Herein, the syntheses of four new Ag(III) corrolato complexes with differently substituted corrolato ligands are presented. A combination of structural, electrochemical, UV/Vis/NIR-EPR spectroelectrochemical, and DFT studies was used to decipher the geometric and electronic properties of these complexes in their various redox states. This combined approach established the neutral compounds as stable Ag(III) complexes, and the one-electron reduced species of all the compounds as unusual, stable Ag(II) complexes. The one-electron oxidized forms of two of the complexes display absorptions in the NIR region, and thus they are rare examples of mononuclear complexes of corroles that absorb in the NIR region. The appearance of this NIR band, which has mixed intraligand charge transfer/intraligand character, is strongly dependent on the substituents of the corrole rings. Hence, the present work revolves round the design principles for the generation of corrole-based NIR-absorbing dyes and shows the potential of corroles for stabilizing unusual metal oxidation states. These findings thus further contribute to the generation of functional metal complexes based on such macrocyclic ligands." @default.
• W2122137790 created "2016-06-24" @default.
• W2122137790 creator A5008474033 @default.
• W2122137790 creator A5010227284 @default.
• W2122137790 creator A5018152460 @default.
• W2122137790 creator A5020335865 @default.
• W2122137790 creator A5048875966 @default.
• W2122137790 creator A5082042652 @default.
• W2122137790 date "2014-10-03" @default.
• W2122137790 modified "2023-10-16" @default.
• W2122137790 title "Silver Corrole Complexes: Unusual Oxidation States and Near-IR-Absorbing Dyes" @default.
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