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- W2122185004 abstract "BiZness as usual? Not exactly! The bismuth atom of the tridentate diphosphinobismuthine (o-(Ph2P)C6H4)2BiCl behaves as a Z rather than L ligand when in the coordination sphere of late transition metals such as gold. The σ-acceptor behavior of Bi is supported by its disphenoid coordination geometry and theoretical studies, which show a Au→Bi interaction. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
- W2122185004 created "2016-06-24" @default.
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- W2122185004 date "2012-03-27" @default.
- W2122185004 modified "2023-10-02" @default.
- W2122185004 title "σ-Accepting Properties of a Chlorobismuthine Ligand" @default.
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- W2122185004 doi "https://doi.org/10.1002/anie.201200854" @default.
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