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• W2122223442 abstract "Kinetic studies of solvent structure effects and solute–solvent interactions on the solvolysis of [Co(NH3)5Cl]2+ complex ion have been investigated spectrophotometrically in binary aqueous mixtures. Three cosolvents were used (acetonitrile, dimethylsulfoxide, and urea) over a wide range of temperatures. Nonlinear plots were found for log(rate constant) against the reciprocal of the relative permitivity of the medium. The enthalpy and entropy of activation (ΔH# and ΔS#) exhibited extrema in the same composition region where the physical properties indicate sharp changes in the structure of the solvent, confirming that the solvent structure is an important factor in determining the solvolytic reactivity. © 2008 Wiley Periodicals, Inc. Int J Chem Kinet 40: 416–422, 2008" @default.
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• W2122223442 date "2008-01-01" @default.
• W2122223442 modified "2023-09-27" @default.
• W2122223442 title "Spectrometric study of solute–solvent interactions for the solvolysis of chloropentaamine cobalt(III) complex in binary aqueous mixtures" @default.
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• W2122223442 doi "https://doi.org/10.1002/kin.20324" @default.
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