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- W2122287638 abstract "Radical developments in silyllithium chemistry: The preparation and X-ray structure of 1, the first compound with geminal Hg-Si-Li bonding, is reported. Compound 1 is obtained by the reaction of (iPr3Si)2SiH2 with [(tBu)2Hg] followed by lithiation in THF. Irradiation of 1 produces [Li(iPr3Si)2Si]. (2), the first silyl radical with an α-Si-Li bond detected by EPR spectroscopy (see spectrum)." @default.
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- W2122287638 date "2002-02-15" @default.
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- W2122287638 title "The Synthesis of the First Compound with Li-Si-Hg Bonding: [{Li(iPr3Si)2Si}2Hg]—a Source for the [Li(iPr3Si)2Si]. Radical" @default.
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- W2122287638 doi "https://doi.org/10.1002/1521-3773(20020215)41:4<649::aid-anie649>3.0.co;2-6" @default.
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