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- W2122318775 abstract "A polymeric thiodiacetate (tda) complex of Ba2+, {Ba[S(CH2COO)2(H2O)3] · 2H2O} n , has been synthesized from aqueous solution in ∼50% yield. The complex crystallizes in the monoclinic P21 /c space group with Z = 4 and the unit cell dimensions a = 13.069 Å, b = 7.350 Å, and c = 12.932 Å. Ba2+ is ten-coordinate, ligated to four tda (O and S) and three aqua ligands. Four distinct binding modes of tda to barium are observed. Each Ba2+ center is coordinated via a tda ligand to four equivalent adjacent Ba2+ centers, creating an extended 2-D polymeric layered structure, with alternate interstitial layers of water. The complex has also been characterized by elemental analysis, FT-IR spectroscopy, and thermogravimetric analysis. 1H and 13C NMR spectroscopic data suggest that the polymeric structure found in the solid state is not present in aqueous solution itself." @default.
- W2122318775 created "2016-06-24" @default.
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- W2122318775 date "2010-07-13" @default.
- W2122318775 modified "2023-10-17" @default.
- W2122318775 title "Self-assembly of a 2-D barium/thiodiacetate coordination polymer in aqueous solution" @default.
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- W2122318775 doi "https://doi.org/10.1080/00958972.2010.499459" @default.
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