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- W2122678135 abstract "The v′ = 0 to 4 vibrational levels of the b 4Σ− state of NO in Ar and Kr matrices were selectively excited in the near infrared by a tunable laser from the metastable a 4Π state previously populated by an ArF excimer laser. One of the decay channels of the b state is a radiationless transition to low vibrational levels of the B 2Π state. By monitoring the time- and energy-resolved B 2Π → X 2Π fluorescence we determined the energies of the b, v′ levels and the propensity rules of the b, v′ &_;rarrw B, v″ transitions. Our results are in good agreement with the previously proposed model assuming an important role for the b 4Σ− state in the radiationless relaxation from the A 2Σ+ (Rydberg) to the final radiative valence states B 2Π and a 4Π." @default.
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- W2122678135 date "1989-12-01" @default.
- W2122678135 modified "2023-09-25" @default.
- W2122678135 title "Spectra and dynamics of the b 4Σ− state of NO in Ar and Kr matrices" @default.
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- W2122678135 doi "https://doi.org/10.1016/0009-2614(89)85201-7" @default.
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