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- W2122732997 abstract "The ternary compound Ba3Li4Sn8 was obtained by slow cooling of a stoichiometric mixture of the elements that was heated at 800 °C for 2 days. Its structure (monoclinic, C2/m, Z=2, a=18.549(1), b=6.685(1), c=6.792(1) Å, V=833.2(2) Å3, R1/wR2=4.03/11.33%) contains one-dimensional chains of 1∞[Sn8]10− made of edge-sharing cyclodecane-like units in their ‘all-chair’ conformations. The cations screen the chains from each other and provide the extra electrons needed for bonding in the chains. The structure and the electron count can be rationalized in terms of the Zintl concept as (Ba2+)3(Li+)4[(2b-Sn2−)2(3b-Sn1−)6], i.e. the compound is an electronically balanced, Zintl phase. Nevertheless, Ba3Li4Sn8 exhibits temperature-independent paramagnetism that is, most likely, of van Vleck type as a result of the very small band gap of about 0.3 eV." @default.
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- W2122732997 date "2002-05-01" @default.
- W2122732997 modified "2023-09-26" @default.
- W2122732997 title "Synthesis, characterization and bonding of Ba3Li4Sn8" @default.
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- W2122732997 doi "https://doi.org/10.1016/s0925-8388(02)00219-0" @default.
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