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- W2122871884 abstract "High-resolution emission spectra of VO have been recorded in the region 3400–19 400 cm−1 using a Fourier transform spectrometer. The molecules were observed from the reaction of VOCl3 with active nitrogen. Two new bands, with origins near 5539.46 and 5551.69 cm−1, are assigned as the 0–0 bands of the 2Φ5/2–2Δ3/2 and 2Φ7/2–2Δ5/2 spin–orbit components (respectively) of a 2Φ–12Δ electronic transition of VO. A rotational analysis of both subbands has been carried out and spectroscopic constants have been extracted. The 12Δ state is known from the previous analysis of the near infrared doublet transitions of VO and the new 2Φ excited state has rotational constants very similar to those of another 2Φ state observed previously [Merer et al., J. Mol. Spectrosc.125, 465 (1987)]." @default.
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- W2122871884 date "2002-02-01" @default.
- W2122871884 modified "2023-10-17" @default.
- W2122871884 title "Fourier Transform Emission Spectroscopy of a New 2Φ–12Δ System of VO" @default.
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- W2122871884 doi "https://doi.org/10.1006/jmsp.2001.8510" @default.
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