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• W2122922118 abstract "Mg and Ca β-diketiminato silylamides [HC{(Me)CN(2,6-iPr2C6H3)}2M(THF)n{N(SiMe3)2}] (M=Mg, n=0; M=Ca, n=1) were studied as precatalysts for the dehydrogenation/dehydrocoupling of secondary amine–boranes R2HNBH3. By reaction with equimolar quantities of amine–boranes, the corresponding amidoborane derivatives are formed, which further react to yield dehydrogenation products such as the cyclic dimer [BH2NMe2]2. DFT was used here to explore the mechanistic alternatives proposed on the basis of the experimental findings for both Mg and Ca amidoboranes. The influence of the steric demand of amine–boranes on the course of the reaction was examined by performing calculations on the dehydrogenation of dimethylamine–borane (DMAB), pyrrolidine–borane (PB), and diisopropylamine–borane. In spite of the analogies in the catalytic activity of Mg- and Ca-based complexes in the dehydrocoupling of amine–boranes, our theoretical analysis confirmed the experimentally observed lower reactivity of Ca complexes. Differences in catalytic activity of Mg- and Ca-based complexes were examined and rationalized. As a consequence of the increase in ionic radius on going from Mg2+ to Ca2+, the dehydrogenation mechanism changes and formation of a key metal hydride intermediate becomes inaccessible. Dimerization is likely to occur off-metal in solution for DMAB and PB, whereas steric hindrance of iPr2NHBH3 hampers formation of the cyclic dimer. The reported results are of particular interest because, although amine–borane dehydrogenation is now well established, mechanistic insight is still lacking for many systems." @default.
• W2122922118 created "2016-06-24" @default.
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• W2122922118 date "2014-04-02" @default.
• W2122922118 modified "2023-09-25" @default.
• W2122922118 title "Hydrogen Release from Dialkylamine-Boranes Promoted by Mg and Ca Complexes: A DFT Analysis of the Reaction Mechanism" @default.
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• W2122922118 doi "https://doi.org/10.1002/chem.201304329" @default.
• W2122922118 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24700384" @default.
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