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- W2122942845 abstract "Chuangxinmycin was shown by chemical correlation to have 35, 4R configuration as shown by 1. It is surprising that I has the opposite absolute configuration as indolmycin (7) with the same carbon skeleton. The carboxyl group of norchuangxinmycin (14) and the methyl group of decarboxychuangxinmycin (18) were found to have preferred equatorial conformations with no observable anomeric effect in the former. Thus the bulkier carboxyl group of chuangxinmycin itself must adopt the equatorial position predominantly, if not exclusively, in solution, a situation already found prevailing in the crystalline state by X-ray diffraction." @default.
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- W2122942845 date "1985-03-01" @default.
- W2122942845 modified "2023-09-26" @default.
- W2122942845 title "The stereochemistry of chuangxinmycin" @default.
- W2122942845 cites W2006677523 @default.
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- W2122942845 doi "https://doi.org/10.1002/cjoc.19850030110" @default.
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