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- W2122975895 abstract "Reaction of the organometallic aqua ion [Cp*Ir(H2O)3]2+ with tert-butyl(trimethylsilyl)amine in acetone yielded a novel trinuclear (μ3-oxido)(μ3-imido)pentamethylcyclopentadienyliridium(III) complex, [(Cp*Ir)3(O)(NtBu)]2+. Single crystal structure analyses show the complex can be isolated both in the double salt (tBuNH3)[(Cp*Ir)3(O)(NtBu)](CF3SO3)3 (1) and in the simple triflate [(Cp*Ir)3(O)(NtBu)](CF3SO3)2 (2). The double salt is stabilized by hydrogen bonding between the tert-butylammonium ion and the three triflate anions. It is the first time that a trinuclear (μ3-oxido)(μ3-imido) transition metal complex has been structurally characterized." @default.
- W2122975895 created "2016-06-24" @default.
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- W2122975895 date "2011-01-01" @default.
- W2122975895 modified "2023-09-24" @default.
- W2122975895 title "Synthesis and X-ray crystal structure of a novel organometallic (μ3-oxido)(μ3-imido) trinuclear iridium complex" @default.
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- W2122975895 doi "https://doi.org/10.1039/c0dt01791d" @default.
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