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• W2123027829 abstract "The interaction of Cu(II) with the protamine scylliorhinine Z3 was studied by means of CD measurements. At a 1:1 molar ratio, three complexes are formed. (1) In the pH range 5–6.5, the results suggest the formation of a five-membered chelate ring through the coordination of two nitrogen atoms, the N-terminal and the contiguous peptide nitrogen. (2) At pH ≥ 6.4, there is involvement of the lateral NH2 group of Arg; at pH 6.5–8, the formation of a 3N cupric complex is strongly suggested. (3) At pH ≥ 8, results indicate the formation of a 4N complex as a major species in Cu(II)-Z3 solution. The transformation from a 2N to a 3N complex, and from a 3N to a 4N complex was followed with the help of the σ(αNH2) → Cu(II) charge-transfer dichroic band transitions. At Cu(II):Z3 molar ratios ≥ 2 and at pH > 8, a new dichroic band appears, indicating the involvement of the tyrosine residue side chain in metal-ion complexation." @default.
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• W2123027829 date "1984-07-01" @default.
• W2123027829 modified "2023-10-17" @default.
• W2123027829 title "Circular dichroic studies on Cu(II) interactions with a protamine, scylliorhinine Z3" @default.
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• W2123027829 doi "https://doi.org/10.1002/bip.360230708" @default.
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