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- W2123106070 abstract "The synthesis and the UV-visible absorption, polarized fluorescence, and MCD spectra of six U-shaped polyenes (1-6) are reported. Qualitative arguments and results of T-electron calculations permit the identification of four excited singlet states and their assignment to mixtures of singly and doubly excited configurations. The hairpin polyenes represent a link between the all-trans polyenes on the one hand and the annulenes and acenes on the other hand: they possess the topology of the former and a geometry near that of the latter. The understanding of their electronic states offers a unified view of low-energy transitions in polyenes and aromatics, which accounts for their differences in a simple and intuitive manner." @default.
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- W2123106070 date "1984-01-10" @default.
- W2123106070 modified "2023-09-24" @default.
- W2123106070 title "ChemInform Abstract: EXCITED SINGLET STATES OF “HAIRPIN” POLYENES" @default.
- W2123106070 cites W3021002046 @default.
- W2123106070 doi "https://doi.org/10.1002/chin.198402058" @default.
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