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• W2123183767 abstract "In this paper, we present a series of different thermotropic discotic columnar liquid crystalline forms of mono-substituted functionalised hexabenzocoronene (HBC) carrying five alkyl chains. Using the Sonogashira coupling reaction, 1-ethynyl-4-alkylbenzene, 1-ethynyl-4-alkoxybenzene, and alkyl-4-ethynyl benzoate groups were introduced into mono-bromohexabenzocoronenes to obtain compounds 5–7. These compounds obtained were characterised by 1H and 13C-NMR, UV-Vis, and MALDI-MS spectrometry. The thermotropic liquid crystalline (LC) properties of the compounds were investigated by polarising optical microscopy (POM), differential scanning calorimetry (DSC), and powder X-ray diffractometry (XRD)." @default.
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• W2123183767 date "2015-09-30" @default.
• W2123183767 modified "2023-10-14" @default.
• W2123183767 title "The functionalised hexa-<i>peri</i>-hexabenzocoronenes by Sonogashira coupling method to modify the columnar mesophase behaviour" @default.
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• W2123183767 doi "https://doi.org/10.1080/02678292.2015.1088081" @default.
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