FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2123194805> ?p ?o ?g. }

• W2123194805 endingPage "1090" @default.
• W2123194805 startingPage "1082" @default.
• W2123194805 abstract "A new synthesis of (8-quinolyl)-5-methoxysalicylaldimine (Hqsal-5-OMe) is reported and its crystal structure is presented. Two FeIII complexes, [Fe(qsal-5-OMe)2]Cl⋅solvent (solvent=2 MeOH⋅0.5 H2O (1) and MeCN⋅H2O (2)) have been prepared and their structural, electronic and magnetic properties studied. [Fe(qsal-5-OMe)2] Cl⋅2 MeOH⋅0.5 H2O (1) exhibits rare crystallographically independent high-spin and low-spin FeIII centres at 150 K, whereas [Fe(qsal-5-OMe)2]Cl⋅ MeCN⋅H2O (2) is low spin at 100 K. In both structures there are extensive π–π and CH⋅⋅⋅π interactions. SQUID magnetometry of 2 reveals an unusual abrupt stepped-spin crossover with T1/2=245 K and 275 K for steps 1 and 2, respectively, with a slight hysteresis of 5 K in the first step and a plateau of 15 K between the steps. In contrast, 1 is found to undergo an abrupt half-spin crossover also with a hysteresis of 10 K. The two compounds are the first FeIII complexes of a substituted qsal ligand to exhibit abrupt spin crossover. These conclusions are supported by 57Fe Mössbauer spectroscopy. Both complexes exhibit reversible reduction to FeII at −0.18 V and irreversible oxidation of the coordinated qsal-5-OMe ligand at +1.10 V." @default.
• W2123194805 created "2016-06-24" @default.
• W2123194805 creator A5025523481 @default.
• W2123194805 creator A5029701197 @default.
• W2123194805 creator A5057309074 @default.
• W2123194805 creator A5073535995 @default.
• W2123194805 creator A5082497099 @default.
• W2123194805 creator A5086640710 @default.
• W2123194805 creator A5087607114 @default.
• W2123194805 date "2012-11-23" @default.
• W2123194805 modified "2023-10-13" @default.
• W2123194805 title "Fe^IIIQuinolylsalicylaldimine Complexes: A Rare Mixed-Spin-State Complex and Abrupt Spin Crossover" @default.
• W2123194805 cites W1510558954 @default.
• W2123194805 cites W1853943609 @default.
• W2123194805 cites W1972025281 @default.
• W2123194805 cites W1972906258 @default.
• W2123194805 cites W1977702858 @default.
• W2123194805 cites W1983486843 @default.
• W2123194805 cites W1983759499 @default.
• W2123194805 cites W1994302934 @default.
• W2123194805 cites W2001517024 @default.
• W2123194805 cites W2005814365 @default.
• W2123194805 cites W2010894285 @default.
• W2123194805 cites W2013339766 @default.
• W2123194805 cites W2014916013 @default.
• W2123194805 cites W2018562515 @default.
• W2123194805 cites W2033925970 @default.
• W2123194805 cites W2040093261 @default.
• W2123194805 cites W2042037132 @default.
• W2123194805 cites W2050867536 @default.
• W2123194805 cites W2053778221 @default.
• W2123194805 cites W2057810447 @default.
• W2123194805 cites W2063124316 @default.
• W2123194805 cites W2064311755 @default.
• W2123194805 cites W2067910711 @default.
• W2123194805 cites W2069509680 @default.
• W2123194805 cites W2071748478 @default.
• W2123194805 cites W2079441647 @default.
• W2123194805 cites W2080447728 @default.
• W2123194805 cites W2091403626 @default.
• W2123194805 cites W2131350133 @default.
• W2123194805 cites W2153592438 @default.
• W2123194805 cites W2161096461 @default.
• W2123194805 cites W2165734921 @default.
• W2123194805 cites W2291635800 @default.
• W2123194805 cites W3136388140 @default.
• W2123194805 cites W4210798485 @default.
• W2123194805 cites W4211095161 @default.
• W2123194805 cites W4249939793 @default.
• W2123194805 doi "https://doi.org/10.1002/chem.201202053" @default.
• W2123194805 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23180614" @default.
• W2123194805 hasPublicationYear "2012" @default.
• W2123194805 type Work @default.
• W2123194805 sameAs 2123194805 @default.
• W2123194805 citedByCount "41" @default.
• W2123194805 countsByYear W21231948052013 @default.
• W2123194805 countsByYear W21231948052014 @default.
• W2123194805 countsByYear W21231948052015 @default.
• W2123194805 countsByYear W21231948052016 @default.
• W2123194805 countsByYear W21231948052017 @default.
• W2123194805 countsByYear W21231948052018 @default.
• W2123194805 countsByYear W21231948052019 @default.
• W2123194805 countsByYear W21231948052020 @default.
• W2123194805 countsByYear W21231948052021 @default.
• W2123194805 countsByYear W21231948052022 @default.
• W2123194805 crossrefType "journal-article" @default.
• W2123194805 hasAuthorship W2123194805A5025523481 @default.
• W2123194805 hasAuthorship W2123194805A5029701197 @default.
• W2123194805 hasAuthorship W2123194805A5057309074 @default.
• W2123194805 hasAuthorship W2123194805A5073535995 @default.
• W2123194805 hasAuthorship W2123194805A5082497099 @default.
• W2123194805 hasAuthorship W2123194805A5086640710 @default.
• W2123194805 hasAuthorship W2123194805A5087607114 @default.
• W2123194805 hasConcept C116569031 @default.
• W2123194805 hasConcept C121332964 @default.
• W2123194805 hasConcept C123299182 @default.
• W2123194805 hasConcept C170493617 @default.
• W2123194805 hasConcept C178790620 @default.
• W2123194805 hasConcept C179104552 @default.
• W2123194805 hasConcept C185592680 @default.
• W2123194805 hasConcept C26873012 @default.
• W2123194805 hasConcept C2777222292 @default.
• W2123194805 hasConcept C2778591166 @default.
• W2123194805 hasConcept C2778696020 @default.
• W2123194805 hasConcept C2780471494 @default.
• W2123194805 hasConcept C35325081 @default.
• W2123194805 hasConcept C42704618 @default.
• W2123194805 hasConcept C544153396 @default.
• W2123194805 hasConcept C55493867 @default.
• W2123194805 hasConcept C70854507 @default.
• W2123194805 hasConcept C8010536 @default.
• W2123194805 hasConcept C97355855 @default.
• W2123194805 hasConceptScore W2123194805C116569031 @default.
• W2123194805 hasConceptScore W2123194805C121332964 @default.
• W2123194805 hasConceptScore W2123194805C123299182 @default.
• W2123194805 hasConceptScore W2123194805C170493617 @default.
• W2123194805 hasConceptScore W2123194805C178790620 @default.
• W2123194805 hasConceptScore W2123194805C179104552 @default.

• next