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• W2123273313 abstract "The trinuclear complex Mn(3)(pko)(4)(CH(3)O)(2)(SCN)(2).CH(3)OH, 1, where Hpko is 2,2'-dipyridylketonoxime, is a rare example of a complex simultaneously containing Mn(II) and Mn(IV). X-ray crystallography and XANES spectroscopy clearly distinguish the Mn(II)(2)Mn(IV) valence isomer from the more commonly observed Mn(III)(2)Mn(II) formulation. Fits to variable-temperature magnetic susceptibility data indicate that the Mn(II) and Mn(IV) are ferromagnetically coupled (J = +6.13 cm(-1)) and that 1 has an S = (13)/(2) ground state." @default.
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• W2123273313 date "2003-03-06" @default.
• W2123273313 modified "2023-10-03" @default.
• W2123273313 title "Models for the Lower S States of Photosystem II: A Trinuclear Mixed-Valent Mn^II/Mn^IV/Mn^II Complex" @default.
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• W2123273313 doi "https://doi.org/10.1021/ic026050h" @default.
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