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- W2123362783 abstract "Abstract The self‐assembly of a metallo‐supramolecular PS‐[Ru]‐PEO block copolymer, where ‐[Ru]‐ is a bis ‐2,2′:6′,2″‐terpyridine‐ruthenium(II) complex, in thin films was investigated. Metallo‐supramolecular copolymers exhibit a different behavior as compared to their covalent counterparts. The presence of the charged complex at the junction of the two blocks has a strong impact on the self‐assembly, effecting the orientation of the cylinders and ordering process. Poly(ethylene oxide) cylinders oriented normal to the film surface are obtained directly regardless of the experimental conditions over a wide range of thicknesses. Exposure to polar solvent vapors can be used to improve the lateral ordering of the cylindrical microdomains. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 4719–4724, 2008" @default.
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- W2123362783 date "2008-06-09" @default.
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- W2123362783 title "Self-assembly of metallo-supramolecular block copolymers in thin films" @default.
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- W2123362783 doi "https://doi.org/10.1002/pola.22805" @default.
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