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- W2123513618 abstract "Abstract Mn 2+ ion was doped into the TiO 2 matrix and its photocatalytic activity was evaluated for the degradation of a mono azo dye methyl orange (MO) and a di‐azo dye brilliant yellow (BY) under UV/solar light. X‐ray diffraction results revealed the phase transformation from anatase to rutile due to the inclusion of Mn 2+ ion into the TiO 2 matrix. All the doped catalysts showed a red shift in the band gap to the visible region. The degradation reaction of the dyes was found to be dependent on its structure. It was found that mono azo dye degrades faster than di azo dye under UV/solar light. The rate constant under identical conditions calculated for the degradation of MO is 2.4 times (under UV light) and 4.5 times (under solar light) higher compared to BY. Among the photocatalysts studied, Mn 2+ (0.06 at.%)‐TiO 2 showed higher activity under both UV and solar light illumination. The synergestic effect in the bicrystalline framework of anatase and rutile effectively suppresses the charge carrier recombination and enhances the photocatalytic activity. The degradation reaction was followed by UV‐visible spectroscopy and the photoproducts formed were analyzed by GC‐MS techniques." @default.
- W2123513618 created "2016-06-24" @default.
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- W2123513618 date "2010-11-01" @default.
- W2123513618 modified "2023-10-16" @default.
- W2123513618 title "Photo Catalytic Degradation of Azo Dyes over Mn2+ Doped TiO2 Catalyst under UV/Solar Light: An Insight to the Route of Electron Transfer in the Mixed Phase of Anatase and Rutile" @default.
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- W2123513618 doi "https://doi.org/10.1002/cjoc.201090356" @default.
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