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- W2123615780 abstract "The reaction of alkylidenecyclopropanes with HCl or with HBr proceeds very smoothly at 120°C to produce the corresponding homoallylic halides stereoselectively in good to excellent yields. For example, the reaction of (1-phenylbenzylidene)cyclopropane, (1-butylpentylidene)cyclopropane and octylidenecyclopropane with hydrochloric acid produced the corresponding homoallylic chlorides, 4-chloro-1,1-diphenyl-1-butene, 4-butyl-1-chloro-3-octene and (E)-1-chloro-3-undecene in 99, 96, and 87% yields, respectively. The reaction of (1-butylpentylidene)cyclopropane with hydrobromic acid yielded 1-bromo-4-butyl-3-octene in 95% yield." @default.
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- W2123615780 date "2003-01-01" @default.
- W2123615780 modified "2023-09-24" @default.
- W2123615780 title "Addition of hydrogen halides to alkylidenecyclopropanes: a highly efficient and stereoselective method for the preparation of homoallylic halides" @default.
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- W2123615780 doi "https://doi.org/10.1016/s0040-4039(02)02722-3" @default.
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